When building a simple salt water battery, consisting of a zinc-anode, copper-cathode and an NaCl-solution, I noticed the following:
When closing the circuit, the current decreases over time. (No surprise, since either charge adds up around the electrodes or $\ce{Na^+}$- and $\ce{Cl^-}$-ions get depleted.) When I gently slide my finger along the zinc-anode (under the water), the measured current increases very little (and continues to decrease over time). When I do the same at the copper-anode, the current increases much more than at the anode (and continues to decrease over time).
I understand that at the zinc-anode $\ce{Zn^2+}$ dissolves into the water. And I understand that at the copper-cathode the electrons will interact with the water, not the $\ce{Na^+}$.
Now, I have 3 questions, where no. 3 is my main question:
Close to the anode: Will $\ce{Cl^-}$-ions just float next to the $\ce{Zn^2+}$-ions independently or will they form $\ce{ZnCl_2}$?
Close to the cathode: What exactly is happening there? Since the voltage I measured is ~0.7V, it can't be electrolysis of water, since 1.23V are required for this to happen. I would assume due to autoprotolysis of water, $\ce{H_3^+O + e^- -> 1/2H_2 + H_2O}$. The autoprotolysis leaves behind an $\ce{^-OH}$. I assume it bonds with the Na, giving $\ce{NaOH}$.
Why do I measure a much greater temporary increase in electric current when I gently stirr the water close to the copper-cathode, compared to stirring close to the zinc-anode? Shouldn't both water-volumes around the two electrodes be equally neutral? On one side, $\ce{Zn^2+}$ gets cancelled out by $\ce{2Cl^-}$, on the other side $\ce{2OH^-}$ get cancelled out by $\ce{2Na^+}$?
Here is the battery:
And here is where I got my ideas for the reactions happening. (I'm not a chemist.)
