As others have said, that's what $\;>\;$ is for. However, if you want to draw special attention to the fact that $\;\neq\;$ applies, then you can use $\;\gneqq \;$ or $\;\gvertneqq \;.$
From the mid 1970s through the early 1990s, I sometimes used (in notes, in homework assignments, etc.) handwritten forms of these symbols and their "less than" versions $\;\lneqq\;$ and $\;\lvertneqq \,,\;$ and they were also sometimes used on the blackboard by the mathematics teachers I had during this period.
Incidentally, even more commonly used back then was the corresponding proper subset relation $\subsetneqq \,,\;$ since the meaning of $\;\subset\;$ varies among authors, with some using this for "subset or equal" and others using this for "proper subset". By using $\;\subsetneqq\;$ for "proper subset" and using $\;\subseteqq \;$ or $\;\subseteq \;$ for "subset or equal", there is no chance of ambiguity.
For what it's worth, these symbols are available in the LaTeX-based software I use, Scientific Workplace. However, they do not appear to be available in MathType (which I sometimes have to use for work-related stuff), but maybe doing something like this will locate them. A quick google image search led me to the Mathematics Stack Exchange question What does this “double less than or equals to” sign mean?, where both $\;\gneqq \;$ and $\;\lneqq\;$ are included in a chart for AMS codes for various inequality symbols.