list = {{32/39, 1/5, 0, 0, 0}, {5/33, 3/5, 1/3, 0, 3/4}};
From the documentation for Max: "Max[{Subscript[x, 1], Subscript[x, 2],…}, {Subscript[y, 1],…},…] yields the largest element of any of the lists." Consequently,
Max[list]
(* 32/39 *)
From the documentation for Position: "Position returns a list of positions in a form suitable for use in Extract, ReplacePart, and MapAt. The form is different from the one used in Part."
pos = Position[list, Max[list]]
(* {{1, 1}} *)
Extract[list, pos]
(* {32/39} *)
If you want the Max of each of the sublists of list
Max /@ list
(* {32/39, 3/4} *)
pos2 = Position[#, Max[#]] & /@ list
(* {{{1}}, {{5}}} *)
Extract[list[[#]], pos2[[#]]] & /@ {1, 2}
(* {{32/39}, {3/4}} *)
Ordering[#1, -1] & /@ list-> {{1}, {5}}. See also here – user1066 Jan 27 '18 at 13:42