You can do this by putting the ℒ and its arguments in boxes, and resizing them. Since you want to be able to add subscripts, I made that an optional argument.
\documentclass{article}
\tracinglostchars=2
\usepackage[paperwidth=10cm]{geometry} % To format the MWE for Tex.SX
\usepackage{iftex} % For \iftutex
\usepackage{settobox} % For \settoboxheight
\usepackage{graphicx} % For \resizebox
\iftutex
\usepackage{newcomputermodern} % For example
%% By default, \mathscr duplicates \mathcal. You wanted a symbol like
%% Boondoxo, which is available as a stylistic set in the STIX fonts.
\setmathfont{STIX Two Math}[
Scale=MatchUppercase,
StylisticSet=1,
range={scr, bfscr}]
\else
\usepackage{lmodern} % For example
\usepackage{amsmath}
\usepackage[scr=boondoxo]{mathalpha}
\fi
\newlength{\LaplaceHeight}
\newbox{\LaplaceArg}
\newcommand\Laplace[2][]{%
\savebox{\LaplaceArg}{(#2)}%
\settoboxheight{\LaplaceHeight}{\LaplaceArg}%
\mathop{\resizebox{!}{\LaplaceHeight}{$\mathscr{L}$}}\nolimits_{#1} \usebox{\LaplaceArg}%
}
\begin{document}
[ \Laplace{\sin t}(s) ]
[ \Laplace[t]{\left{ \frac{1}{t+1} \right} }(s) ]
\end{document}

This version matches only the height and not the depth. To match your illustration more closely, but drop below the baseline, you can instead resize to the argument’s total height and lower by its depth:
\documentclass{article}
\tracinglostchars=2
\usepackage[paperwidth=10cm]{geometry} % To format the MWE for Tex.SX
\usepackage{iftex} % For \iftutex
\usepackage{settobox} % For \settoboxtotalheight, \settoboxdepth
\usepackage{graphicx} % For \resizebox
\iftutex
\usepackage{newcomputermodern} % For example
%% By default, \mathscr duplicates \mathcal. You wanted a symbol like
%% Boondoxo, which is available as a stylistic set in the STIX fonts.
\setmathfont{STIX Two Math}[
Scale=MatchUppercase,
StylisticSet=1,
range={scr, bfscr}]
\else
\usepackage{lmodern} % For example
\usepackage{amsmath}
\usepackage[scr=boondoxo]{mathalpha}
\fi
\newlength{\LaplaceHeight}
\newlength{\LaplaceDepth}
\newbox{\LaplaceArg}
\newcommand\Laplace[2][]{%
\savebox{\LaplaceArg}{(#2)}%
\settoboxtotalheight{\LaplaceHeight}{\LaplaceArg}%
\settoboxdepth{\LaplaceDepth}{\LaplaceArg}%
\mathop{\raisebox{-\LaplaceDepth}{\resizebox{!}{\LaplaceHeight}{$\mathscr{L}$}}}\nolimits_{#1} \usebox{\LaplaceArg}%
}
\begin{document}
[ \Laplace{\sin t}(s) ]
[ \Laplace[t]{\lef

As several have mentioned in the comments, scaling the ℒ makes it look too heavy. You could possibly scale it only along the vertical axis, but that doesn’t look good either.
Here’s an alternative you might like better, which defines a normal-size \laplace and a double-sized \Laplace, scaling up the latter from a lighter weight of the font family. It requires LuaLaTeX or XeLaTeX.
\documentclass{article}
\tracinglostchars=2
\usepackage{newcomputermodern} % For example
\setmathfont{KPMath-Regular}[ Scale=MatchUppercase, range={scr,bfscr}]
\setmathfontface\bigmath{KPMath-Light}[Scale=2.0]
\newcommand\laplace{\mathop{\mathscr{L}}\nolimits}
\newcommand\Laplace{\mathop{\bigmath{ℒ}}\nolimits}
\begin{document}
[ \laplace{\sin t}(s) ]
[ \Laplace_t {\left{ \frac{1}{t+1} \right} }(s) ]
\end{document}

\newcommand{\Laplace}[2][t]{\mathop{}\!\mathscr{L}_{#1}\!\left\{#2\right\}}. Then in the document body you say\[ \Laplace{ \frac{1}{1+t} }(s) \]or\[ \Laplace{ \sin t }(s) \]. You can even use different arguments such as\[ \Laplace[u]{ \exp(-u) }(x) = \frac{1}{1+x} \]– Ruixi Zhang Jan 29 '21 at 22:40\mathop{}\!do? – Miguel Fernando Macias Macias Jan 29 '21 at 22:50\Laplacetakes one mandatory argument, which is the function you throw into the Laplace transform. It also accepts an optional argument, which you can use to replace the subscript. The syntax is\Laplace[<optional arg>]{<mandatory arg>}. – Ruixi Zhang Jan 29 '21 at 22:56tex = MathTex(r" \Laplace{ t } ", tex_template=my_template)– Miguel Fernando Macias Macias Jan 29 '21 at 23:02\Laplace{ t }– Miguel Fernando Macias Macias Jan 29 '21 at 23:04\documentclass{article} \usepackage{mathrsfs} \newcommand{\Laplace}[2][t]{\mathop{}\!\mathscr{L}_{#1}\!\left\{#2\right\}} \begin{document} You can write \[ \Laplace{\sin t}(s) \quad\mbox{and}\quad \Laplace{\frac{1}{t+1}}(s) \] \end{document}runs fine on my computer. – Ruixi Zhang Jan 29 '21 at 23:06