From this question we know that aligning the equal signs in
A = B = C
D = E = F
is done by using alignat, not align.
If we have instead
A = W + M = C
B = i + \iota = D
how can the equal signs as well as the + signs be aligned?
From this question we know that aligning the equal signs in
A = B = C
D = E = F
is done by using alignat, not align.
If we have instead
A = W + M = C
B = i + \iota = D
how can the equal signs as well as the + signs be aligned?
The important rule for all *align* environments is rlrlrlrl…, meaning that alternating columns are left-, right-, left-, right-, …-aligned.
Such basic question as you posted can be easily written in many ways (#1 = #2, #3 = #4):
\documentclass{article}
\usepackage{amsmath}
\begin{document}
\begin{alignat*}{3} % #1
A & = W & {}+{} & M && = C \\
B & = i & {}+{} & \iota && = D
\end{alignat*}
\begin{alignat*}{3} % #2
A & = W && {} + M && = C \\
B & = i && {} + \iota && = D
\end{alignat*}
\begin{alignat*}{3} % #3
A & ={} & W +{} & & M & = C \\
B & = & i +{} & & \iota & = D
\end{alignat*}
\begin{alignat*}{3} % #4
A & ={} & W & +{} & M & = C \\
B & = & i & +{} & \iota & = D
\end{alignat*}
\end{document}

