An infrared LED just emits its light (primarily) in the infrared range as described by this Wikipedia article. Any emitted radiated signal (including sound) has both a frequency and a wavelength. The frequency = the velocity of the signal through space divided by its wavelength (F = V / W), or vice-versa: (W = V / F). The natural frequency of light, infrared or visible is far, far higher than 38 KHz; around 4 x 10^14 Hz.
38 KHz is simply a convenient chopping frequency for switching the LED on and off so the sensor can distinguish between infrared in sunlight, for instance, which is relatively constant - from that emitted by the LED. Your circuitry would have to create the 38KHz chopping signal.