You're using a wide lens (39mm) with a long focus distance (11m).
Even at f/1 the depth of field is 5 meters wide which still covers most of your scene.
Either use longer lens, or shorter focus distance.
You can check your DoF here: https://www.dofmaster.com/dofjs.html
You can preview the depth of field in viewport:

39mm compared to 135mm lens with f/1 and focus at 6 meters

Note that you can also use a f-stop that is less than 1.0
A different way to get selective focus, with the exact same field of view, is to use a much larger sensor size, which in turn will make you use a longer lens to have the same field of view, hence making the focusing distance more critical and with less depth of field. For example, if you make the sensor twice as large, you will need a lens that is also twice as large for the same field of view.
Read:
How do I set focus range?
Also, when it comes to depth of field it is important to work in real world dimensions. If the objects are larger than in real life, then your distances to the camera will be much larger, making it hard to get selective focus.