Questions tagged [carbocation]

Carbocations are species bearing a positive charge on carbon. They are intermediates generally formed during organic reactions, which can be stabilised by various electronic effects. Less stable carbocations are capable of undergoing rearrangements to form more stable carbocations in the course of a reaction.

Carbocations (a portmanteau of carbon and cation) are one of the three main reactive intermediates in organic reactions (carbocations, carbanions and radicals). They are species which have a positive charge on a carbon.

The positively-charged carbon in a carbocation only has six electrons in its valence shell, and hence is electron-deficient or electrophilic, making it extremely susceptible towards nucleophilic attack. Carbocations generally show $\mathrm{sp^2}$ hybridisation and are therefore trigonal planar about the positive carbon.

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Why are isomers difficult to separate?

I recently learned that attempts to compare the spectra of two isomers of $\ce{C_3H_3^+}$ were frustrated by the difficulty of separating the two species. What makes these isomers difficult to separate?
Dan
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Why doesn't the carbocation form on the carbon that is attached to the ethyl group in this reaction?

Why doesn't the carbocation form on the carbon that is attached to the ethyl group in this reaction? Subsequently, why doesn't the $\ce{Cl-}$ attack the carbon that is attached to the ethyl group? Is a tertiary carbocation less stable than a…
nickb
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Carbocation ring expansion jump

is the given rearrangement possible {major product}? from cyclo butane derivative to cyclohexane derivative.
Mrigank
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