The two-sided bandwidth would be 125MHz. (+/-62.5 MHz). This is given as the symbol rate (which is the data rate for BPSK) times one plus the roll-off factor (so $100(1.25)=125$). At RF the occupied bandwidth would be 125 MHz and at baseband as a low pass signal extending from DC to 62.5 MHz which is referred to as the one-sided bandwidth.
If sampling at baseband, with two ADC’s for receiver (for I and Q) and one DAC for transmitter (only need I if BPSK) then the minimum sampling rate to just meet Nyquist would be 125 MHz. In practice we need more than that allow for realizable filtering (20% more or so as a trade with filter complexity). Given the waveform is BPSK, you can use I only for the transmitter (single DAC) but you will need two in the receiver given inevitable offsets in phase and frequency between the transmitter and receiver. The complex receiver baseband would allow for phase measurement from symbol to symbol and with that carrier offset correction can be implemented. Another option for the receiver is to use a real digital IF frequency and the do the downconversion to baseband digitally. In this case the IF frequency must be greater than 62.5 MHz with additional margin to allow for filtering. A 125 MHz digital IF and 500 MHz sampling rate would be a reasonable choice.
The minimum sampling rate in the Tx is 125 MHz plus room for filtering as described. Two samples per symbol (200 MHz) would be a reasonable choice, and may simplify the transmitter timing given the integer multiple of the symbol rate. This decision is a trade between digital complexity and power consumption and the analog reconstruction filter after the DAC. Using a lower number of samples per symbol has the advantage of a longer time span in the pulse shaping filter, resulting in a higher stopband rejection given the same number of coefficients, but together with that a tighter analog reconstruction filter is also needed given the closer proximity of images at the output of the DAC. For a specific demonstration of this, see DSP.SE #51088. One common solution is to interpolate to a higher rate after the pulse shaping filter as the interpolation filter there can often be simpler in complexity than the pulse shaping filter used.
The sampling rate used in the Rx can be completely different than Tx if desired. (In between the waveform is analog so the receiver can sample that waveform to meet its own requirements regardless of how it was sampled in the transmitter).