No, it will not be valid. Think about where the exponent comes from. Also, if you have different distributions, how can there be only an arbitrarily picked $f_{Z_i}$ in your (1)? That doesn't make sense. You should probably build up a little more intuition here!
If you're working on ordered statistics, calculating the PDF of $Z_\min=\min(\{Z_i\})$ for i.i.d. RVs is probably something you want to do at least once yourself to get yourself warm with the common tricks when dealing with collections of random variables.
The derivation of $f_{Z_\min}$ is actually pretty straightforward. I'll give you a start!
\begin{align}
f_{Z_\min}(z) &=\frac{\mathrm d}{\mathrm d\,z}F_{Z_\min}(z) \tag2\\
&=\frac{\mathrm d}{\mathrm d\,z}P({Z_\min}\le z)\tag3\\%
&=\frac{\mathrm d}{\mathrm d\,z}P(Z_1\le z \,\wedge\, Z_2\le z \,\wedge\,Z_3\le z \,\wedge\,\ldots\,\wedge\,Z_N\le z )\tag4\\%
\end{align}
Now, at this point your calculation starts depending on whether $Z_i$ are independent! Try with independent variables $Z_i, \quad i=1,\ldots,N$ first. Remember the definition of what it means for random variables to be independent. Then, don't forget to apply the chain rule of derivatives.