By way of enrichment here is another algebraic proof using basic
complex variables. As I pointed out in the comment this identity is
very simple using a convolution, so what follows should be considered
a learning exercise.
We seek to compute
$$\sum_{k=0}^n {2k\choose k} {2n-2k\choose n-k}.$$
Introduce the integral representation
$${2n-2k\choose n-k}
= \frac{1}{2\pi i}
\int_{|z|=\epsilon} \frac{(1+z)^{2n-2k}}{z^{n-k+1}} \; dz.$$
We use this to obtain an integral for the sum. Note that when $k>n$
the pole at zero disappears which means that the integral is
zero. Therefore we may extend the sum to infinity, getting
$$\frac{1}{2\pi i}
\int_{|z|=\epsilon}
\frac{(1+z)^{2n}}{z^{n+1}}
\sum_{k\ge 0} {2k\choose k} \frac{z^k}{(1+z)^{2k}}\; dz.$$
Recall that
$$\sum_{k\ge 0} {2k\choose k} w^k = \frac{1}{\sqrt{1-4w}}$$
so this becomes
$$\frac{1}{2\pi i}
\int_{|z|=\epsilon}
\frac{(1+z)^{2n}}{z^{n+1}} \frac{1}{\sqrt{1-4z/(1+z)^2}} \; dz
\\ = \frac{1}{2\pi i}
\int_{|z|=\epsilon}
\frac{(1+z)^{2n}}{z^{n+1}} \frac{1+z}{\sqrt{(1+z)^2-4z}} \; dz
\\ = \frac{1}{2\pi i}
\int_{|z|=\epsilon}
\frac{(1+z)^{2n+1}}{z^{n+1}} \frac{1}{1-z} \; dz.$$
Extracting coefficients we get
$$\sum_{q=0}^n {2n+1\choose q} =
\frac{1}{2} 2^{2n+1} = 2^{2n} = 4^n.$$
Apparently this method is due to Egorychev.
Addendum.
The Lagrange inversion proof goes like this. We seek to compute
$$\frac{1}{2\pi i}
\int_{|z|=\epsilon}
\frac{1}{z^{k+1}} \frac{1}{\sqrt{1-4z}} \; dz.$$
Put $1-4z = w^2$ so that
$z= \frac{1}{4} - \frac{1}{4} w^2$ and $dz = -\frac{1}{2} w \; dw$
to get
$$-\frac{1}{2\pi i}
\int_{|w-1|=\epsilon}
\frac{4^{k+1}}{(1-w^2)^{k+1}} \frac{1}{w} \frac{1}{2} w \; dw
\\ = -\frac{2^{2k+1}}{2\pi i}
\int_{|w-1|=\epsilon}
\frac{1}{(1-w)^{k+1}} \frac{1}{(1+w)^{k+1}} \; dw
\\ = -\frac{2^{2k+1}}{2\pi i}
\int_{|w-1|=\epsilon}
\frac{1}{(1-w)^{k+1}} \frac{1}{(2+w-1)^{k+1}} \; dw
\\ = -\frac{2^k}{2\pi i}
\int_{|w-1|=\epsilon}
\frac{1}{(1-w)^{k+1}} \frac{1}{(1+(w-1)/2)^{k+1}} \; dw
\\ = -\frac{2^k (-1)^{k+1}}{2\pi i}
\int_{|w-1|=\epsilon}
\frac{1}{(w-1)^{k+1}} \frac{1}{(1+(w-1)/2)^{k+1}} \; dw.$$
Extracting coefficients we obtain
$$- 2^k (-1)^{k+1} {k+k\choose k} \frac{(-1)^k}{2^k}
= {2k\choose k}.$$
It is not difficult to see that in the above substitution the image of
a small radius counterclockwise circle around the origin in the $z$
plane is a small radius circle around $w=1$ also traversed
counterclockwise.
A similar calculation may be found at this
MSE link.