This question is related to this question (for which I still don't know the answer). There I state this result but for Riemann-Stieltjes like this:
If $f,\alpha$ are continuous and $\alpha$ increasing, $f\geq0$ and $\int_a^b f(x)d\alpha=0$ then $f=0$.
I tried to follow the same proof but I never use the continuity of $\alpha$, so I think is wrong...which makes me wonder if this is even true! Seems true because $\alpha$ is increasing, so in the sums we have a term that will be $>0$