What's a model
Models in model theory are sets which interpret a first-order language (the usual logical symbols $=$, $\land$, $\lor$, $\neg$, $\forall$, $\exists$, and additional function, relation, and constant symbols.)
only one model of the axioms (up to an isomorphism)
In model theory, the term for this is categorical. In first-order logic one isn't able to control the size of models of a theory (this is the Loewenheim-Skolem theorem), so we usually say that a theory $T$ is $\kappa$-categorical if all of its models of size $\kappa$ (for $\kappa$ an infinite cardinal) are isomorphic. A fundamental result is Morley's 1965 categoricity theorem (this inspired Shelah, for example, to embark on his programme on classification theory): if a theory in a countable language is categorical in some uncountable $\kappa$, it's categorical in all uncountable $\kappa$.
Theories are just collections of sentences; a complete theory is one whose models all satisfy the same sentences. For example, the theory of algebraically closed fields in characteristic zero is complete. It's also $\aleph_1$-categorical, but not countably categorical, because there are countable algebraically closed extensions of $\mathbb{Q}$ of different transcendence degree.
Now, while probability spaces are outside the purview of classical first-order logic, you might be interested in recent work on continuous model theory (see section 16 of this paper for probability spaces in particular.)