The only way I know of to calculate this would be to brute force it, and it's quite long so I won't go all the way through it, but this should be enough to get your started.
The first card in the deck is guaranteed to not be a repeat. For the second card dealt, there are three cards in the deck which would match the first, and 51 remaining cards, so 3/51 chance. Since we only want to consider the case where it does not match, we will use 48/51 chance of not getting a match.
The third card in the deck can't match the second. Since the first and second cards weren't the same, we know there are 3 cards that do match, so 47/50 chance of not matching.
Now it gets more complicated. For the fourth card, it can't match the third card, but the third and first card could be the same card. It doesn't matter - yet - if the fourth card matches the first or second because that doesn't affect the probability here. It only matters if the first and third card matches because that affects the probability that the third card repeats. The probability that the first and third cards matched is 3/50. So the probability is either 46/49 (third card is not the same as the first) with probability 3/50 or 47/49 with probability 47/50.
So far, the probability that there is not a repeated card for the first four cards is 48/51 * 47*50 * (46/49 * 3/50 + 47/49 * 47/50) or just under 85%, assuming I haven't made any silly math errors.
For the fifth card you must consider the probability that the fourth card matches either the first or second card or neither and combine these probabilities as we did for the fourth card. As you get further into the deck you must consider the different ways this can happen. For instance, you must consider the probability that the previous card matched 1, 2, 3, or 4 times previously. Once you get to the end of the deck you will have the value you are looking for.