Since each "chunk" of three consecutive terms consists of
$$\frac{1}{3n+1}+\frac{1}{3n+2}-\frac{2}{3n+3}$$
Then you should combine them into a single term:
$$\frac{(3n+1)(3n+3)+(3n+2)(3n+3)-2(3n+1)(3n+2)}{(3n+1)(3n+2)(3n+3)}$$
which condenses down to
$$\frac{9n+5}{(3n+1)(3n+2)(3n+3)}$$
And so your Riemann Sum should be
$$\sum_{n=1}^\infty \frac{9n+5}{(3n+1)(3n+2)(3n+3)}$$
Now, if you need a hint on how to actually evaluate it once you have it as a Riemann Sum, here is what you should do. Let $S(a)$ be a function defined as
$$S(a)=\sum_{n=1}^\infty \frac{(9n+5)a^{3n+3}}{(3n+1)(3n+2)(3n+3)}$$
Then, as you can see, when you find $S'''(a)$, you get
$$S'(a)=\sum_{n=1}^\infty \frac{(9n+5)a^{3n+2}}{(3n+1)(3n+2)}$$
$$S''(a)=\sum_{n=1}^\infty \frac{(9n+5)a^{3n+1}}{(3n+1)}$$
$$S'''(a)=\sum_{n=1}^\infty (9n+5)a^{3n+1}$$
This is easier to evaluate. Once you have a formula for this, you need only integrate $S'''(a)$ three times to find $S(a)$ in terms of $a$. Then notice that your sum is equal to $S(1)$.
However, since you mention that these are contest problems that would need to be solved quickly, here is what my strategy would be: you can rule out $A$ and $C$ immediately, since $A$ is the value of the alternating harmonic series (which this is obviously not), and since there are no factorials in the sum, suggesting that $e$ is not involved in the final value.
Now you must decide between $B$ and $D$. Notice that our $S'''(a)$ would turn into a geometric series should we decide to evaluate it. This means that some part of $S'''(a)$ should contain the expression
$$\frac{1}{1-a}$$
which suggests that the integrals of $S'''(a)$ would contain logarithms. Thus the answer should (I'm guessing) be $\ln 3$.
Am I right?