This one has a really cute trick, namely that the integrand is equal to
$$\int_a^b e^{-xt} \, dt$$
as you can verify by a direct computation. This means we can write a double integral and change the order of integration, yielding
\begin{align*}
\int_a^b \int_0^{\infty} e^{-xt} \, dx \, dt &= \int_a^b -\frac{e^{-xt}}{t}\big|_{x = 0}^{x = \infty} \, dt \\
&= \int_a^b \frac 1 t \, dt \\
&= \ln \frac b a
\end{align*}
By the way, the integral you mention does converge. It's bounded by $e^{-ax}$ as $x \to \infty$, and bounded at the origin because $e^{-ax} - 1 = -ax + O(x^2)$.