If we have a consistent and axiomatizable extension of PA, which we'll call $T$, I'm wondering if it's possible to have a sentence $\phi$ such that $T \vdash Prov_T(\phi)$ but $T \nvdash \phi$ where $Prov_T(x)$ expresses "$x$ is provable in $T$".
Note very importantly that we assume $T$ contains "sufficient induction" such that it satisfies the following derivability conditions:
(1) "reflection" which is if $T \vdash \sigma$ then $T \vdash Prov_T(\sigma)$ and (2) a "formal" version of modus ponens such that $T \vdash Prov_T(a) \land Prov_T(a \rightarrow b) \rightarrow Prov_T(b)$ for any sentences $a$ and $b$.
My intuition is that there is such a sentence $\phi$ since @Noah Schweber points out in this post that soundness might not hold.
On the other hand, I also think Lob's theorem is relevant and some adaptation of it might actually prove that $T \vdash Prov_T(\phi)$ then $T \vdash \phi$ if we use the derivability to adapt Lob's theorem. Any hints?