As other people suggested, you can define any transform you want. The question you need to answer, "why are you defining that?".
In the case of the Fourier transform, the definition of the transform is inspired by Fourier series. Thus, it makes sense to why somebody would want to consider that. After such a transform is introduced, it is then natural to ask for various properties this transform has. The Fourier transform has plenty of very nice properties that make it very valuable in many instances.
The Laplace transform is very similar to the Fourier transform. It is almost a "real"-version of the Fourier transform, so it is again natural to consider it. It also comes with its own nice properties, which is not surprising since it is so similar to the Fourier transform.
There are a few other transforms. For instance, there is something called the Hankel transform. Why was it invented? Because people realized that the Laplace/Fourier transform can be used, among many other things, to solve certain differential equations. Inspired by this, certain mathematicians thought of what other analogue transforms would aid in solving various important differential equations. The Hankel transform was introduced to specifically deal with Bessel-like differential equations, as they are frequently studied in physics.
Necessity drives innovation. Thus, before you go on your own path to invent a new transform, the question you should ask is, "what can my transform be used for solving". Otherwise, if it is an uninspired random transform, then it will probably not be useful in any circumstance and just sit there alone by itself without any need to study it.