I'd like to expand on a piece of Jim's answer:
Recall that a linear action of $G$ on a vector space $V$ gives a homomorphism $G \to GL(V)$. If $V$ is $d$-dimensional over $\mathbb R$ then picking a basis gives an isomorphism $GL(V) \simeq GL_d(\mathbb R)$. Since $GL_n(\mathbb C)$ acts on $\mathbb C^n \simeq \mathbb R^{2n}$ this would give a homomorphism $GL_n(\mathbb C) \to GL_{2n}(\mathbb R)$.
Let's consider in detail the case of $n=2$. We begin by selecting a basis for the real-vector space $\Bbb C^{2}$:
$$
\mathcal B = \{v_1,v_2,v_3,v_4\} = \{(1,0),(i,0),(0,1),(0,i)\}.
$$
Now, suppose that we are given a matrix
$$
A = \pmatrix{b_{11} & b_{12}\\b_{21} & b_{22}} +
i\pmatrix{c_{11} & c_{12}\\ c_{21} & c_{22}}.
$$
The referenced isomorphism from $GL_2(\Bbb C)$ to $GL_{4}(\Bbb R)$ that comes from picking a basis is the map that produces the matrix of the transformation $x \mapsto Ax$ relative to $\mathcal B$.
We can see what this matrix looks like by seeing what $x \mapsto Ax$ does to each column-vector. For instance, we have
$$
Av_1 = \left(\pmatrix{b_{11} & b_{12}\\b_{21} & b_{22}} +
i\pmatrix{c_{11} & c_{12}\\ c_{21} & c_{22}}\right) \pmatrix{1\\0}
\\ =
\pmatrix{b_{11} + c_{11}i\\ b_{21} + c_{21}i} = b_{11}v_1 + c_{11}v_2 + b_{21}v_3 + c_{21} v_4
$$
and can therefore see that the first column of the matrix of $x \mapsto Ax$ should be $(b_{11}, c_{11},b_{21},c_{21})^T$. Proceeding in a like fashion, we can see that the full matrix for this map will be
$$
\left[\begin{array}{cc|cc}b_{11} & -c_{11} & b_{12} & -c_{12}\\
c_{11} & b_{11} & c_{12} & b_{12}\\
\hline
b_{21} & -c_{21} & b_{22} & -c_{22}\\
c_{21} & b_{21} & c_{22} & b_{22}\\
\end{array}\right]
$$
In other words, one version of the isomorphism that you're looking for is
$$
\pmatrix{b_{11} & b_{12}\\b_{21} & b_{22}} +
i\pmatrix{c_{11} & c_{12}\\ c_{21} & c_{22}}
\mapsto \pmatrix{b_{11} & -c_{11} & b_{12} & -c_{12}\\
c_{11} & b_{11} & c_{12} & b_{12}\\
b_{21} & -c_{21} & b_{22} & -c_{22}\\
c_{21} & b_{21} & c_{22} & b_{22}\\}.
$$