Proposition Let $G$ be a finite group, $n$ a non-zero integer, then the map $f: G \rightarrow G$ defined by $f(g)=g^n$ is a bijection if and only if gcd$(n,|G|)=1$.
Proof Assume $f$ is bijection and let $p$ be a prime dividing both $|G|$ and $n$. By Cauchy's Theorem, one can find a $g \in G$ of order $p$. But $f(g)=g^n=(g^p)^{\frac{n}{p}}=1$, so $g=1$ as $f$ is bijective, a contradiction.
If $|G|$ and $n$ are relatively prime, then by Bézout's Theorem, we can find $a,b \in \mathbb{Z}$ with $1=a|G|+bn$. Hence for each $g \in G$, $g=g^1=g^{a|G|+bn}=(g^{|G|})^a \cdot (g^b)^n=(g^b)^n$, showing that $f$ is surjective. Since $G$ is finite, it follows that $f$ is injective.
If $n$ and $|G|$ are not relatively prime, then one can use character theory of finite groups over $\mathbb{C}$ to say something about "$\sqrt[n]{g}$". One can define, assuming $n$ is positive, $\vartheta_n(g)=\#\{h \in G: h^n=g\}$. This is a class function on $G$ (constant on conjugacy classes) and hence one can write $\vartheta_n=\sum_{\chi \in Irr(G)}\nu_n(\chi)\chi$, where $\nu_n(\chi) \in \mathbb{C}$ are uniquely determined. So if you know these values of $\nu_n$ for each $\chi \in Irr(G)$, you know the numbers $\vartheta_n$. More on this theory can be found in many textbooks, for example that of I.M. Isaacs, Character Theory of Finite Groups, Chapter $4$, Products of Characters, page $49$ and following. Or see Y.G. Berkovich, L.S. Kazarin, E.M. Zhmud Characters of Finite Groups, page $152$, IV.5-7.