Consider the unordered couple of sets $A,B \in \mathcal{P}([n])$ such that $A \cup B = [n]$, $A \neq B$. I would like to prove that the number of such couples is:
$$\frac{3^n-1}{2}$$
I derived that expression by enumerating the solutions for the first values of $n$, and also considering the sum of the number of those couples for all different values of $n$ over $\mathcal{P}([m])$:
$${2^m \choose 2} = \sum_{n=0}^m {m \choose n}\frac{3^n-1}{2}$$
(this is easy to show using the binomial expansion).
I have checked OEIS A003462 where they count the number of couples $A,B \in \mathcal{P}([n])$ with $A \cap B = \emptyset$ and $A \neq \emptyset$ or $B \neq \emptyset$, with the same $\frac{3^n-1}{2}$ result, but it's not the same thing and I was not able to adapt that reasoning.