For all $n$, the constant polynomial
$$c(x) = \frac{1}{2}$$
is the best approximation for the function $f_{\alpha}$.
To see this, we show that for every polynomial $p : [0,1] \to \Bbb R$ the following holds:
$$\sup_{x \in [0,1]} |f_{\alpha} (x) - c(x)| \le \sup_{x \in [0,1]} |f_{\alpha} (x) - p(x)|$$
First: obviously
$$\sup_{x \in [0,1]} |f_{\alpha} (x) - c(x)|= \frac{1}{2}$$
So it is enough to prove that for any polynomial $p$ the inequality
$$\sup_{x \in [0,1]} |f_{\alpha} (x) - p(x)|\ge \frac{1}{2}$$ holds. There are two cases:
- First case: $p( \alpha ) \le 1/2$. In this case you have
$$|f_{\alpha} (\alpha) - p(\alpha)| = |1-p(\alpha)| = \left|\frac{1}{2} + \frac{1}{2} - p( \alpha) \right| = \frac{1}{2} + \left( \frac{1}{2} - p( \alpha) \right) \ge \frac{1}{2}$$
In particular the supremum is larger or equal to $1/2$.
- Second case: $p( \alpha ) > 1/2$. In this case consider arbitrary $x \in [0 ;\alpha )$. You have
$$\sup_{x \in [0,1]} |f_{\alpha} (x) - p(x)| \ge \sup_{x \in [0,\alpha)} |f_{\alpha} (x) - p(x)| \ge \lim_{x \to \alpha^-} |f_{\alpha} (x) - p(x)| = p(\alpha) > \frac{1}{2}$$
This completes the proof.
Remark: the polynomial minimizing the quantity $\sup_{x \in [0,1]} |f_{\alpha} (x) - p(x)|$ need not to be unique. There may be more than one, but I think that the constant polynomial is the simplest one.