Yes. The set of all values for the $U$s is $[0, 1] \times [0, 1] \times \ldots \times [0, 1]$, an $n$-dimensional cube.
The "face" defined by
$$
U_1+\ldots+U_n = 1
$$
is a pyramid-like shape in $n$-dimensions known as an $(n-1)$-simplex, which is the thing that mathematicians generally agree is the generalization of a triangle to higher dimensions.
Let's call this specific $(n-1)$-simplex by the name $K$.
Every point in the set defined by
$$
U_1+\ldots+U_n \leq 1
$$
is actually in the "cone" on $K$ from the origin, i.e., it's pyramid-like, with the origin as the apex. (BTW, the "pyramid" in the 3D case isn't a traditional Egyptian pyramid -- it's actually a tetrahedron, but I think that was what you intended).
That "cone on the set $K$" is defined as the set of all linear combinations of the form
$$
(1-t)\cdot (0, \ldots, 0) + t \cdot (v_1, \ldots, v_n),
$$
where $t$ ranges from $0$ to $1$ and $(v_1, \ldots, v_n) $ is a point of $K$. If you have some nonzero point
$$
(u_1, \ldots, u_n)
$$
in the set defined by
$$
U_1+\ldots+U_n \leq 1
$$
you can let
$$
t = u_1+\ldots+u_n
$$
and
$
v_i = \frac{u_i}{t}
$,
which gives the correspondence between this cone and the set you're interested in.
If you actually draw out all this stuff in the cases $n = 2, 3$, you'll pretty quickly see how it generalizes.