The Poincaré duality is defined in Greub's Multilinear algebra (1967) in Chapter 6, §2 as a isomorphism between $\bigwedge V$ and $\bigwedge V^*$, where $V$ is a finite-dimensional vector space, $V^*$ is its dual, and $\bigwedge V$ is the exterior algebra of $V$. More precisely, the isomorphism maps $\bigwedge^k V$ to $\bigwedge^{n-k} V^*$, $n=\dim V$. Greub's definition has nothing to do with cohomology groups of manifolds and is based entirely on multilinear algebra. I have tried reading Chapter 6 and quickly realised I would need to study the entire book to understand the definition. I am only interested in the cases $V=\mathbb R^n$ where $n\le5$, and I only need to see what the isomorphism looks like on the standard basis of $\bigwedge \mathbb R^n$ and $\bigwedge (\mathbb R^n)^*$.
For example, let $e_1,e_2,e_3$ denote the standard basis of $\mathbb R^3$ and $e_1^*,e_2^*,e_3^*$ the standard basis of $({\mathbb R}^3)^*$. Then the basis of $\bigwedge\mathbb R^3$ consists of 1, $e_1,e_2,e_3$, $e_1\wedge e_2$, $e_2\wedge e_3$, $e_3\wedge e_1$, $e_1\wedge e_2\wedge e_3$ and the basis of $\bigwedge(\mathbb R^3)^*$ consists of 1, $e_1^*,e_2^*,e_3^*$, $e_1^*\wedge e_2^*$, $e_2^*\wedge e_3^*$, $e_3^*\wedge e_1^*$, $e_1^*\wedge e_2^*\wedge e_3^*$. The isomorphism maps, say, $e_1^*$ to $e_2\wedge e_3$ or perhaps $-e_2\wedge e_3$. I am not sure which sign is the right one. That is, I already know what the isomorphism looks like but only up to a sign. So, my question is what the correct signs are in the mapping Greub uses.
My second question is how Poincaré duality as defined by Greub is related to Hodge duality. The latter depends on a bilinar form on $(\mathbb R^n)^*$ but I am only interested in the form defined by $\langle e_i^*,e_i^*\rangle=1$ and $\langle e_i^*,e_j^*\rangle=0$ if $i\ne j$. The Hodge duality maps $\bigwedge^k(\mathbb R^n)^*$ to $\bigwedge^{n-k}(\mathbb R^n)^*$, so it is restricted to the exterior algebra of $(\mathbb R^n)^*$, but its effect is somewhat similar to that of the Poincare duality. For instance, the Hodge duality maps $e_1^*$ to $e_2^*\wedge e_3^*$. If I define a map $\mathcal{R}:\bigwedge (\mathbb R^n)^*\to\bigwedge \mathbb R^n$ in the obvious way by removing $*$ from the relevant basis vectors, e.g. $\mathcal{R}(e_1^*\wedge e_2^*)=e_1\wedge e_2$, would the Poincaré duality $\mathcal{P}:\bigwedge (\mathbb R^n)^*\to\bigwedge \mathbb R^n$ and the Hodge duality $\mathcal{H}$ be related by $\mathcal{P}(a)=\mathcal{R}(\mathcal{H}(a))$ where $a\in \bigwedge (\mathbb R^n)^*$.
EDIT:
Despite what Bruno Joyal says, I think $\mathcal{P}(a)=\mathcal{R}(\mathcal{H}(a))$ is valid without any sign adjustment, provided that $\langle,\rangle$ is defined as above. I define the Hodge dual (or Hodge star *, $\mathcal{H}(a)=*a$) by
$a\wedge(*b)=\langle a,b\rangle \omega$,
where $\omega=e_1^*\wedge\dots\wedge e_n^*$ is the standard element of $\bigwedge^n(\mathbb R^n)^*$, and $\langle a,b\rangle=\det(\langle a_i,b_i\rangle)$ for $a=a_1^*\wedge\dots\wedge a_k^*$ and $b=b_1^*\wedge\dots\wedge b_k^*$, which can be replaced by 1 in calculations with the basis vectors thanks to my choice of the inner product.
I don't understand the definition of Poincaré duality but Greub does give the formula for computing the duals,
$\mathcal{P}(e_{\nu_1}^*\wedge\dots\wedge e_{\nu_p}^*)=(-1)^{\sum_{i=1}^p(\nu_i-i)}e_{\nu_{p+1}}\wedge\dots\wedge e_{\nu_n}$,
where $\nu_1<\nu_2<\dots < \nu_n$, and $(\nu_{p+1},\dotsc,\nu_n)$ is complementary to $(\nu_1,\dots,\nu_p)$. As far as I can see, the factor $(-1)^{\sum_{i=1}^p(\nu_i-i)}$ is the sign of the permutation that takes $(\nu_1,\dots,\nu_n)$ to $(1,\dots,n)$, but $a$ and $*a$ are related in the same way for the basis elements of $\bigwedge(\mathbb R^n)^*$. I just need to use the map $\mathcal{R}$ to go to the primary space. Hence, $\mathcal{P}(a)=\mathcal{R}(\mathcal{H}(a))$. I confirmed that by calculations for $n=2,3,4$. The fact that $*a$ is not an involution doesn't really matter.