Note that $\binom{n}{k}$ counts the number of ways to choose $k$ elements from an $n$-element set; having done this, there are $k$ ways to "mark" a special element from those $k$.
In other words, $k\binom{n}{k}$ is the number of ways to choose a subcommittee of size $k$ from a group of $n$ people, and name one of the $k$ subcommittee members as chair.
Summing over these, you are looking at all of the possible ways to choose a non-empty subcommittee from $n$ people, and name a chair.
But, we can count this another way: by first choosing a chairman in one of $n$ ways, then choosing any subset (empty or non-empty) of the remaining $n-1$ people; there are $2^{n-1}$ ways to do this. So, it should be the case that
$$
\sum_{k=1}^{n}k\binom{n}{k}=n2^{n-1}.
$$