The $5$-adic expansion of $5^{-1}$ is simply $5^{-1}$. Seems you are overthinking things.
Just like how multiplying real numbers by powers of $10$ shifts their decimal expansions to the left or right as appropriate, and just like how multiplying a Laurent series $\sum a_nx^n$ by powers of $x$ shift their coefficients to the left or right, so too will multiplying a $p$-adic number by powers of $p$ shift its $p$-adic digital representations, in the same exact manner as you would expect.
Since $9^{-1}=\overline{210234}21024_5$, we get $45^{-1}=\overline{210234}2102.4_5$, or
$$\frac{1}{45}=4\cdot5^{-1}+2\cdot5^0+0\cdot5^1+1\cdot5^2+2\cdot5^3+\cdots$$
Are you sure about the shifting to the right? Please explain it to me if possible. I'm really in the dark regarding this stuff.
thank you
– user108680 Nov 23 '13 at 05:42