I don't think there is a known closed form for the zero. The function $f(x) = \sum_{k=0}^{\infty} x^{2^k}$ was studied by Mahler in his paper On a special function, Journal of Number Theory, Vol. 12, Issue 1, Feb. 1980, pp. 20–26 (PDF link) and he studied the zeros of its partial sums in the paper On the zeros of a special sequence of polynomials, Mathematics of Computation , Vol. 39, No. 159, Jul. 1982, pp. 207-212 (PDF link).
You can be sure that there are exactly two real zeros since
- $f''(x) > 0$ (at most two roots),
- $f(0) = 0$ (found one),
- $f'(0) > 0$ (changes sign here),
- $f(x) \to +\infty$ as $x \to -1^-$ (must change sign again).