The potential number of pairwise different clauses with $n$ variables and the number of sorted sets of clauses:

Your proposed list of unsatisfiable cores is intractable long for any meaningful number of variables.
A brute-force way to find such unsatisfiable cores would be to enumerate the sets with a given number of variables and clauses. To be an unsatisfiable core, the set of clauses has to be unsatisfiable as a whole. This can be checked by using a SAT solver or enumerating up to $2^n$ variable assignments.
Unsatisfiable cores are usually created or extracted with respect to a given Boolean formula rather than compiling a complete list of all conceivable cores.