As far as I understand it, once a subexpression gets replaced, it can't get replaced again. Try this:
a*b /. {a -> a, a -> 1, b -> c}
resulting in
a*c
The first replacement just replaces a with a, but since that expression has already been changed, it is ignored after that. So the Rule a -> 1 is only applied to other parts of the expression (in this case the b), and those other parts don't depend on a, so nothing changes. Finally, b gets replaced with c. (By the way, in somewhat-advanced Mathematica programming, this fact can be taken advantage of in many clever ways. Here is an example by Mr. Wizard, provided in the comments.)
So you're kind of right and kind of not. The Rules are applied sequentially, but the rules are not applied to the new expressions resulting from previous replacements.
Here's another interesting example:
a b c /. {a -> b, b -> c, c -> d}
% /. {a -> b, b -> c, c -> d}
% /. {a -> b, b -> c, c -> d}
(* b c d *)
(* c d^2 *)
(* d^3 *)
In the first case, the a instance is replaced by b, but it is not in turn replaced by c. However, the original b is replaced by c. And so on. To do all of them at once, use ReplaceRepeated:
a b c //. {a -> b, b -> c, c -> d}
(* d^3 *)
(Be careful of this one, because it can run into infinite recursions.) For completeness, note that ReplaceRepeated does not act the same as a sequence of ReplaceAlls if the list of Rules are different:
a b c //. {a -> b, c -> d, b -> c}
a b c /. {a -> b} /. {c -> d} /. {b -> c}
(* d^3 *)
(* c^2 d*)
Finally, as noted by Daniel Lichtblau in a comment, if you do want to apply the two rules to get different expressions, do this:
2 x + y /. {{x -> 3}, {x -> 4}}
(* {6 + y, 8 + y} *)
Alternatively, do
2 x + y /. # &/@ {x -> 3, x -> 4}
or
2 x + y /. List/@{x -> 3, x -> 4}
a*b /. {a -> a, a -> 1, b -> c}. The first replacement just replacesawitha, but since that expression has already been changed, it is ignored after that, so theRulea - > 1is only applied to other parts of the expression, and there are no morea's, butbgets replaced withc. So you're kind of right and kind of not. – march Jan 29 '16 at 18:51Listof rule lists. `In[265]:= 2 x + y /. {{x -> 3}, {x -> 4}}Out[265]= {6 + y, 8 + y}`
– Daniel Lichtblau Jan 29 '16 at 18:56ReplaceAll(/.) doesn't apply several rules to the same part of a given expression. For that case you want to useReplaceRepeated(//.). In your case however this won't chance the output sincex -> 3changesxto be3so there is no morexfor the second rule to match against – Sascha Jan 29 '16 at 18:563) When you see good questions and answers, vote them up by clicking the gray triangles, because the credibility of the system is based on the reputation gained by users sharing their knowledge. Also, please remember to accept the answer, if any, that solves your problem, by clicking the checkmark sign! – Jan 29 '16 at 18:58
ReplaceAllworks. – march Jan 29 '16 at 19:01ReplaceAllis somewhat hidden in the "Details" section of the documentation – Sascha Jan 29 '16 at 19:06