This works:
p = (Cos[2 θ] (-Cos[α] d[β] + d[γ]) - I d[θ]) Sin[2 ϕ];
D[p, {Thread[d[{α, β, γ, θ, ϕ}]]}]
(*
==> {0, -Cos[α] Cos[2 θ] Sin[2 ϕ], Cos[2 θ] Sin[2 ϕ], -I Sin[2 ϕ], 0}
*)
Edit in response to modified question
As it stands now, the goal seems to be simply to extract the totally antisymmetric tensor $\omega$ as defined in the question. This can be done by inserting the canonical unit vectors in place of the d[...] in your expression. I am assuming that the entire expression is in fact representable as a single tensor of a rank consistent with the number of factors d[...].
Since Mathematica has the built-in function TensorWedge, the task is very easily achieved if I assume that the input expression also makes use of TensorWedge to write the differential form. So here are some examples of forms to be transformed:
Clear[d];
example =
Cos[x]^2 TensorWedge[d[x], d[y], d[z]] -
Sin[x]^2 TensorWedge[d[y], d[x], d[z]];
example2 =
Sin[θ] Cos[θ] Sin[ϕ] TensorWedge[d[θ],
d[α], d[β]] + 2 Cos[2 θ] TensorWedge[d[α], d[γ], d[ϕ]];
Now define the function that extracts the coefficients, and apply it to p as defined earlier, and then to the other examples:
diffCoeff[expr_, vars_] := Module[
{n = Length[vars], rank, dd = Thread[d[vars]]},
rank = Length[FirstCase[expr, _TensorWedge, {1}, Infinity]];
TensorReduce[expr /. Thread[dd -> IdentityMatrix[n]]]
]
diffCoeff[p, {α, β, γ, θ, ϕ}]
{0,-Cos[α] Cos[2 θ] Sin[2 ϕ],Cos[2 θ] Sin[2 ϕ],-I Sin[2 ϕ],0}
exampleTensor = diffCoeff[example, {x, y, z}];
dr = Thread[d[{x, y, z}]]
(* ==> {d[x], d[y], d[z]} *)
Assuming[{x ∈ Reals, d[x] ∈ Arrays[{3}], d[y] ∈ Arrays[{3}], d[z] ∈ Arrays[{3}]},
1/6 Simplify@
TensorReduce[
Sum[exampleTensor[[i, j, k]] TensorWedge[dr[[i]], dr[[j]],
dr[[k]]], {i, 3}, {j, 3}, {k, 3}]]]
$d[x]\wedge d[y]\wedge d[z]$
Above, I first extracted the coefficient tensor $\omega$ as exampleTensor, and then put it back as a differential form using a straightforward Sum that implements the rule in the question. The simplified result agrees with what is expected.
The last example is copied from the question, and I'll print out the coefficient matrix for it (note that it doesn't contain the factorial factor $1/3!$):
diffCoeff[example2, {α, β, γ, θ, ϕ}] //Normal
{{{0,0,0,0,0},{0,0,0,Cos[θ] Sin[θ] Sin[ϕ],0},{0,0,0,0,2 Cos[2 θ]},{0,-Cos[θ] Sin[θ] Sin[ϕ],0,0,0},{0,0,-2 Cos[2 θ],0,0}},{{0,0,0,-Cos[θ] Sin[θ] Sin[ϕ],0},{0,0,0,0,0},{0,0,0,0,0},{Cos[θ] Sin[θ] Sin[ϕ],0,0,0,0},{0,0,0,0,0}},{{0,0,0,0,-2 Cos[2 θ]},{0,0,0,0,0},{0,0,0,0,0},{0,0,0,0,0},{2 Cos[2 θ],0,0,0,0}},{{0,Cos[θ] Sin[θ] Sin[ϕ],0,0,0},{-Cos[θ] Sin[θ] Sin[ϕ],0,0,0,0},{0,0,0,0,0},{0,0,0,0,0},{0,0,0,0,0}},{{0,0,2 Cos[2 θ],0,0},{0,0,0,0,0},{-2 Cos[2 θ],0,0,0,0},{0,0,0,0,0},{0,0,0,0,0}}}
TensorSymmetry[%]
Antisymmetric[{1, 2, 3}]
Because of the antisymmetry, the large tensor in Normal form can be reduced to a much smaller representation using
exampleTensor2 =
diffCoeff[example2, {α, β, γ, θ, ϕ}];
SymmetrizedArrayRules[exampleTensor2]
(*
==> {{1, 2, 4} ->
Cos[θ] Sin[θ] Sin[ϕ], {1, 3, 5} ->
2 Cos[2 θ], {_, _, _} -> 0}
*)
There are only two independent nonzero elements in this representation.