In response to your first question, Feyre has explained in great detail the procedure to get whatever you wanted. But it seems, you are still unable to do it.
And I suspect this problem arise when you were trying to plot x'[t] from NDSolve. This issue was also addressed by Feyre in his comments and suggested to use NDSolveValue.
Eqn = a*(x'[t])^2 + b + c *x[t] - m *x''[t] == 0;
a = 0.00713; b = 0.0175; c = -12.141; m = 0.044;
sol = NDSolveValue[ {Eqn, x[0] == 0, x'[0] == 0}, x[t], {t, 0, 2}]
Show[Plot[Evaluate[sol], {t, 0, 2}, PlotStyle -> {Red},
PlotLegends -> {"x[t]"}],
Plot[Evaluate[D[sol, t]], {t, 0, 2}, PlotStyle -> {Green},
PlotLegends -> {"x'[t]"}], PlotRange -> All]

Now to see whether the Mathematica agree with the so-called experimental value you stated,
CEData = (Evaluate[sol] /. t -> 0.233)
0.00251695
which is far from close to the data you provided. So, I also checked with Maple,
restart;with(plots):
eq := a *( diff(x(t),t))^2 + b + c * x(t) - m* diff(x(t),t$2);
a:= 0.00713; b := 0.0175; c := -12.141; m := 0.044;
ics:=D(x)(0)=0,x(0)=0;
sol:=dsolve({eq,ics},numeric);
odeplot(sol,[[t,diff(x(t),t)],[t,x(t)]],0..2,color=
[red,green],axes=boxed,legend=["x'(t)","x(t)"]);

sol(0.233)
0.00251697716038847
I think you should recheck your differential equation along with the parameter values.
If you are interested in finding the exact solution then you should follow Nasser's answer?
TWOinitial conditions. Could you? – zhk Jan 07 '17 at 14:37Then the two initial conditions become x[0]=0, x'[0]=0
– John Jan 07 '17 at 14:46