Set is specially overloaded for Part in order to allow in-place modification of the expressions:
a = x -> 2;
a[[1]] = 1; a
1 -> 2
It is documented on the Documentation page for Part (the first point under "Details" section):
You can make an assignment like t[[spec]]=value to modify any part or sequence of parts in an expression. »
Your function hoge doesn't Hold its arguments and hence passes to Set the extracted variable (a Symbol) instead of the Part expression what explains why it "works" for you:
hoge[x_, y_] := Hold[x = y]
a = x -> 2;
hoge[a[[1]], a[[2]]]
Hold[x = 2]
For your particular purpose the simplest approach is to replace Rule by Set:
Clear[x, y, z]
{x -> 2, y -> 5, z -> x + y} /. Rule -> Set
{2, 5, 7}
Another method is to Apply Set effectively replacing the head Rule by Set:
Clear[x, y, z]
Set @@@ {x -> 2, y -> 5, z -> x + y}
{2, 5, 7}
Inside of Do:
Clear[x, y, z]
Do[Set @@ a, {a, {x -> 2, y -> 5, z -> x + y}}];
{x, y, z}
{2, 5, 7}
Do[Set @@ a, {a, {x -> 2, y -> 5, z -> x + y}}]but it will fail anyway, as soon asx/y/zhave values. related: 28610, also see links in 103628 – Kuba May 16 '17 at 09:07awitha[[2]], and it is the failure. – selpo May 16 '17 at 09:43