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I have a list of expressions

listOfStuff = {-(b^(3/2)/Sqrt[7 \[Pi]]), b^(3/2)/Sqrt[7 \[Pi]]}

When I try to access the first element of this list like so

First[listOfStuff]

This yields

-(b^(3/2)/Sqrt[7 \[Pi]])

If I try to access it either of the following two ways

listOfStuff[[0]]
Part[listOfStuff, 0]

I get

List

The notebook literally just prints "List". I'm new to Mathematica but not new to programming languages in general. I really don't understand what is going on here. Any help understanding this would be appreciated.

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