Have a look at the Mathematica calculation
z = {{1}, {0}};
o = {{0}, {1}};
Ψ = Sin[θ]*KroneckerProduct[z, z, z] +
Cos[θ]*KroneckerProduct[o, o, o] // MatrixForm
Ψt =
Transpose[{{Sin[θ]}, {0}, {0}, {0}, {0}, {0}, {0}, {Cos[θ]}}] // MatrixForm
ρ = Ψ.Ψt;
ρ // MatrixForm
After calculation at the last step we shall get a $6\times 6$ matrix ρ. But Mathematica is showing me $$\begin{bmatrix}\sin[\theta] \\ 0\\0\\0\\0\\0\\0\\ \cos[\theta]\end{bmatrix} . \begin{bmatrix} \sin[\theta] & 0 & 0 & 0 & 0 & 0 & 0& \cos[\theta]\end{bmatrix}$$
I like to get the in matrix form for farther calculations. Might be I have done some mistake, that I do not know. What changes to do?
Thank you for your help.