Using ${\rm Li}(x) := \int_2^x dt/\log t$, as usual, here is an elementary argument that ${\rm Li}(x) > x/\log x$ for $x \geq 7$, so no need to appeal to a lower bound valid only starting at $e^5 \approx 148.4$ as in the Rosser-Schoenfeld paper from the comments.
For $x > 1$, let $f(x) = {\rm Li}(x) - x/\log x$. Then
$$
f'(x) = \frac{1}{\log x} - \left(\frac{\log x - 1}{(\log x)^2}\right) = \frac{1}{(\log x)^2} > 0,
$$
so $f$ is increasing on $(1,\infty)$. Since $f(7) \approx .1145$, for $x \geq 7$ we have $f(x) \geq f(7) > 0$, so ${\rm Li}(x) > x/\log x$.
Since $f(6) \approx -.1716$, $f$ vanishes somewhere between 6 and 7. That happens slightly below 6.58: from PARI, I find $f(6.58) \approx .000076$.
Similarly, for $x > 1$ let $g(x) = {\rm Li}(x) - x/\log x - x/(\log x)^2$. Then
$$
g'(x) = \frac{2}{(\log x)^3}
$$
so $g$ is increasing on $(1,\infty)$. From PARI, $g(20) \approx -.044$ and $g(21) \approx .028$, so ${\rm Li}(x) > x/(\log x) + x/(\log x)^2$ for $x \geq 21$. Since $g(20.65) \approx .0030005$, $g$ vanishes slightly below 20.65.
More generally, from repeated integration by parts
$$
{\rm Li}(x) = \sum_{n=1}^N \frac{(n-1)!x}{(\log x)^n} + \int_2^x \frac{N!\, dt}{(\log t)^{N+1}} + c_N
$$
for $N \geq 0$ and $x > 1$, where $c_N$ is a constant.
Therefore the difference
$$
g_N(x) := {\rm Li}(x) - \sum_{n=1}^N \frac{(n-1)!x}{(\log x)^n}
$$
has $g_N'(x) = N!/(\log x)^{N+1} > 0$, so $g_N$ is increasing on $(1,\infty)$. Find an $x_0$ where $g_N(x_0) > 0$ and then
${\rm Li}(x) > \sum_{n=1}^N (n-1)!x/(\log x)^n$ for $x \geq x_0$.