How about this? (But I will be enlarging $Mbl$ by a functor that is not full.)
Let's make a category whose objects can be called abstract $\sigma$-algebras. I'll call the category $\Sigma$.
A $\Sigma$-object consists of
(1) a set $F$,
(2) a symmetric binary relation on $F$ called "disjointness", and
(3) a rule "countable disjoint union" that assigns to each countable family $x:S\to F$ of pairwise disjoint elements an element $D(x)\in F$. (Here $S$ is a finite or countably infinite set, and "pairwise disjoint" means that $x(i)$ and $x(j)$ are disjoint if $i\neq j$.)
This is subject to some axioms. Call $x:S\to F$ and $x':S'\to F$ disjoint if $x(i)$ is always disjoint from $x'(i')$. The axioms are as follows:
(A1) If $E\in F$ is disjoint from $x(i)$ for every $i\in S$ then $E$ is disjoint from $D(x)$. Note that A1 implies that if $x:S\to F$ and $x':S'\to F$ are disjoint then $D(x)$ and $D(x')$ are disjoint.
(A2) For $x:\lbrace i_0\rbrace \to F$, $D(x)=x(i_0)$.
(A3) The disjoint union of disjoint unions is the disjoint union.
A $\Sigma$-morphism $T:F\to F'$ is a map of sets from $F$ to $F'$ that preserves disjointness and commutes with disjoint union in the sense that:
(M1) Whenever $E_1$ and $E_2$ are disjoint elements of $F$ then $T(E_1)$ and $T(E_2)$ are disjoint.
(M2) When $x:S\to F$ is a countable pairwise disjoint family (i.e. when $D(x)$ is defined) then $D(T\circ S))$ (which is defined, by (M1)) is equal to $T(D(S))$.
There is a functor $\iota:Mbl \to \Sigma^{op}$, taking each measurable space $X$ to the set $M_X$ of all measurable subsets of $X$ (with the usual notions of disjointness and countable disjoint union) and taking a measurable map $X\to Y$ to the map $M_Y\to M_X$ given by $E\mapsto f^{-1}(E)$.
The functor $\iota$ is not faithful, but it becomes faithful if we restrict attention to those measurable spaces in which points are determined by which measurable sets they belong to, which is not a big deal.
Here is the desired representing object. Let $P$ be the set $[0,+\infty]$, declare any two elements to be disjoint, and for a countable family $S\to P$ let $D(x)$ be the sum.
So a $\Sigma$-morphism $F\to P$ is simply a rule assigning an element of $[0,+\infty]$ to each element of $F$ and satisfying additivity for finite and countably infinite (abstract) disjoint unions. In particular a $\Sigma^{op}$-morphism $P\to\iota(X)$ is precisely a measure on the measurable space $X$.
Note that the structure on a set (abstract disjointness relation and abstract disjoint union) that makes it an abstract $\sigma$-algebra brings with it some things. There is an element $0=D(\emptyset)$ that is disjoint from all elements. There is a weak partial ordering: $E'\le E$ iff there exist $E''$ disjoint from $E'$ such that $E$ is the disjoint union of $E'$ and $E''$.
The functor $\iota$ is not full, but some of the new morphisms between measure spaces that appear are things that one might want to use sometimes. If $X$ is a measurable space and $A\subset X$ is a measurable subset, which we then consider as a measurable space in its own right, then there is a "wrong-way" map $\iota(X)\to \iota(A)$ that takes any measurable subset $E\subset A$ to $E\subset X$.
The object $\iota(\emptyset)$ is both initial and terminal.