The Saturn V payload mass to LEO was 118,000 kg. Wikipedia has a decent comparison of Super-heavy launch systems with a payload mass to LEO of 50,000 kg or more. None are in current use, and only two systems are in development.
There is also a "Heavy" lift launch system list which includes the Delta IV and Ariane 5 you mentioned. The top operational system is the Atlas V HLV with a mass to LEO of 29,420 kg and a Mass to GTO of 13,000. However, it has never been launched and the United Launch Alliance claims it needs a 30 month lead-time to produce the Heavy Launch Vehicle variant of the Atlas V.
Next on the list with mass to LEO/GTO:
- Delta IV Heavy: 22,950/12,980 kg, 3/4 successful launches.
- Proton: 21,600/6,360 kg (comparatively lower GTO due to launch location), 295/335 successful launches
- Ariane 5: 21,000/10,050 kg, 54/58 successful launches.
So the answer is there are no currently operational launch systems which approach the Saturn V Mass to LEO capability.