Sure, but only if earth had a gravitational field comparable to that of a neutron star (and your jar would need to be fairly indestructible). In this article, it is stated that the Chandra X-Ray Observatory has discovered$^1$ a neutron star with an atmosphere with a height of about $10\ \text cm$. Yes, ten centimeters. So, if you filled your jar with air and put it on the surface of the star, most of it will be vacuum (when I say vacuum, I mean really low pressure as you would expect in space) with the air on the bottom (probably in another phase). The materials in this atmosphere would be vastly different to air on earth and under huge pressure, far greater than air on earth (see image below: "thin carbon atmosphere").
EDIT: Added the above text and image below that was found during a search of something related, and found it very interesting, so I have added it to this answer.
But to answer your exact question, you should first note that gases that are in the highest part of earth's atmosphere have small kinetic energies (usually not enough to escape into space) that are far less than the kinetic energy of gases close to the surface of the earth.
The average kinetic energy of gas atoms/molecules close to the surface of earth are far greater and certainly not small enough to stay at the bottom of the jar without bouncing to the top.
Also note that technically, a jar with a gas inside will have a slightly greater pressure at the bottom than the top due to earth's gravity. But this pressure difference will be so small that it’s virtually undetectable.
$^1$ From the actual NASA press release:

Ref: https://bigthink.com/hard-science/the-moon-is-inside-earths-atmosphere-claims-study/
– ProbingOmega Jan 25 '23 at 18:41