In QED the field strength tensor $F_{\mu\nu}$ is given by the commutator of the covariant derivatives $$D_\mu=\partial_\mu-ieA_\mu$$ where $A_\mu$ is the gauge field. Explicitly we have
$$[D_\mu,D_\nu]\psi=ieF_{\mu\nu}\psi$$
Using this relation one can derive the standard result
$$F_{\mu\nu}=\partial_\mu A_\nu-\partial_\nu A_\mu.$$
However I only get this result if terms of the form $A_\mu\partial_\nu$ vanish. Is there some mathematical reason why this happens (some cancellation somewhere) or the action of the derivative on the field, in which case what is the physical reason behind the assumption of these terms vanishing?