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I read that electrons revolving around the nucleus have a current due to the revolution, and it has a formula

$$I = \frac{ve}{2\pi r}$$ where $v$ is the velocity of the electron, $e$ is the charge, and $r$ is the radius of revolution.

enter image description here

So how is possible that despite currents due to that revolution, the net current is $0$ for any object that doesn't have a potential difference across its ends? i.e., why doesn't the current just add up and create a total current for every object?

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    Welcome to Physics Stack exchange! This is a great first question you have posted – tryst with freedom Mar 10 '21 at 08:33
  • Are you actually asking about magnetism, as many answers imply? Or are you just wondering why an amperemeter inserted into a straight wire doesn't measure anything, eben though all "electrons" are constantly "moving", as you show in the image? – Peter - Reinstate Monica Mar 11 '21 at 16:32

8 Answers8

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What you heard ( you do not give a link) is a simplified classical electricity and magnetism model for the atom, but it has been known for decades that atoms, electrons, and nuclei can only be correctly modeled using quantum mechanics. In the image you show, in classical electricity and magnetism, the electron would lose energy and fall on the nucleus neutralizing it. It is the reason Bohr developed his model demanding angular momentum quantization, which was superseded by the theory of quantum mechanics. See my answer here.

In quantum mechanics, the electrons are in orbitals around the nucleus, not in orbits. Their location is given by a probability distribution given by the complex conjugate squared of the wavefunction, $Ψ^*Ψ$. It is not a consecutive track to be able to contribute with other tracks and add up to a classical current because the electrons are in fixed energy levels about each nucleus.

In contrast, in lattices, one can have a classical microscopic view of current because in the quantum mechanical model of conduction band electrons, they are free to move over all the lattice and thus give a measurable current.

anna v
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  • just a further question. The quantum electron still has KE and some time average sense of velocity. Is it possible to think that the electrons sense of velocity is like an equilibrium distribution of particle velocity in an ideal gas and more like temperature, an internal energy unavailable for useful work. A classical concept of current would be available to do useful work, so even classically thinking (with qm providing the equilibrium distribution), there is no "current". – OzzieO Mar 09 '21 at 14:02
  • @OzzieO to get a current you need velocity in the same direction. This is not possible with the electrons of atoms in QM bound states , unless there are lattice solutions, like the band theory. – anna v Mar 09 '21 at 14:09
  • yes, that is why I drew the analogy to the KE(velocity) of a particle in an equilibrium ideal gas, there is no net vector direction but there is still a velocity (temperature). Just trying to draw a classical analogy involving current as available to do useful work. – OzzieO Mar 09 '21 at 14:18
  • Is it even reasonable to think of electrons bound to an atom to be particles moving around the nucleus in a pattern given by the orbital? – jamesqf Mar 09 '21 at 21:57
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    You don't need to appeal to QM to answer this question. Even in the classical model, the idea of the currents "adding up" is wrong. – BlueRaja - Danny Pflughoeft Mar 10 '21 at 00:28
  • @BlueRaja-DannyPflughoeft I am pointing out that currents are not explainable with an atomic model classically, to make clear that It is not possible for a classical atom to be stable and build up into solids – anna v Mar 10 '21 at 04:27
  • Doesn't classic QM give a wrong picture too? We can in this context calculate the wavefunction of the system (though it is an approximation) but the more basic is QFT and in this context, a calculation of the state of the atom can't be made because of the fact that calculations in QFT are usually done with perturbation theory and this presupposes that there are free field initially and finally. The last thing obviously isn't true for an electron and a proton interacting to form a bound state (for which QFT is thus not suited). – Deschele Schilder Mar 10 '21 at 09:06
  • QFT is a higher level model of quantum mechanics, based on the postulates of quantum mechanics. It can be used in various ways. In condensed matter, in nuclear physics the basic field making up the model are not the fields of the standard model. Other quantum models are needed for solid state lattices,as the band theory of solids, and it works very well. – anna v Mar 10 '21 at 09:22
  • above for @DescheleSchilder – anna v Mar 10 '21 at 09:40
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    In fact, there are currents in single atoms in QM. For example, ground state of boron has nonzero angular momentum and magnetic moment. This is exactly due to the probability current that's non-zero at all points except the $z$ axis. – Ruslan Mar 10 '21 at 22:14
  • @Ruslan the question is about electrical current, that can build up as a classical charge current.. probablilty currents are a QM story – anna v Mar 11 '21 at 05:05
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The current, You are looking at, is what call a Bound current. The bound current is different from the free current (which you get when you put a battery across the conductor).

It is often useful to distinguish between bound currents and free currents. Bound currents are currents associated with molecular or atomic magnetic moments, including the intrinsic magnetic moment of particles with spin. These are the molecular current loops envisioned by Ampère, the source of the magnetization we have just been considering. Free currents are ordinary conduction currents flowing on macroscopic paths – currents that can be started and stopped with a switch and measured with an ammeter.

You ammeter measure the amount of charge that flows through it in unit time, In bound current as you see the charges are bound so they can't contribute to like free current do.

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Remember that current density (or more precisely probability current density) is a vector field. It has a magnitude and direction at each point. Two atoms with the same magnitude current density at a point may add together or cancel out, depending on the direction. With random orientations over large numbers of atoms, the average is usually very close to 0.

There are cases where the orientation is not random. Those lead to ferromagnetism.

Dale
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The current is an analogy in the sense that you have a moving charge. However, this current is not like currents in a circuit where the electrons are moving due to a potential difference. The current is just due to the orbit of the electron around the nucleus, similar to how there is a "mass current" due to the Moon orbiting the Earth.

why doesn't the current just add up and create a total current for every object?

Because this "current" isn't flowing throughout entire objects. We are just looking at electrons revolving around single atoms. However, there can be object-wide effects, typically through magnetic moments of these "currents" depending on how they align.

BioPhysicist
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It is common for the magnetic effects of electron spin (rotation) to add up -- in ferromagnets -- but the effects of orbital angular momentum (revolution) generally average to zero. You must dig pretty deep into QM to understand the mechanisms that favor aligned electron spins in some materials, but these specific mechanisms do not apply to molecules. Even if you were to consider pairs of molecules or ions with magnetic moments attributable to orbital angular momentum, the coupling of their magnetic moments would average to zero when you integrate over relative positions of the molecules.

Bert Barrois
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    +1, but be careful about saying this does not apply to molecules. Some strong ferromagnets are ceramics, which is to say metal oxides. They are ferromagnets because the orbitals of the magnetic metal atoms couple with the orbitals of oxygen. Because of the crystal structure, adjacent atoms are O M O M ... The O's keep all the M's aligned. – mmesser314 Mar 09 '21 at 14:47
  • Electron spin has nothing to do with rotation though. It is not actually spinning, it has an unrelated property called spin. If only they had named it 'gwarp' it would have been less easy to mix up. – Stian Mar 09 '21 at 23:30
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Remember that current is the amount of charge passing through some area per unit time. So whether you'll have current or not will depend on your chosen area.

When we talk about current through a wire, we assume the area to be the planes perpendicular to the length of the wire. Is there any net flow of electron through these planes? There isn't. Without an applied potential, electrons are just randomly shooting left and right across the cross section of the wire. So there is no net current

Ryder Rude
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Current happens due to drift of charged particles, i.e. if you were able to tag each charges you would be able to see these charged particles physically moving in the material, that results in current. Here the electron is bound. This is just like a circular wire connected end to end and since its "bound" you cant divert these electron using a different wire. Hence these charge motion does constitute current but its not conductive current.

Whatever I explained is purely a classical picture, it turns out strictly speaking this is not true with microscopic particles like electrons. In a more standard theory called Quantum Mechanics, these microscopic particles are no longer revolving around the nuclear, its just present everywhere around the nucleus SIMULTANEOUSLY.

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This can be explained with classical mechanics:

In most materials the orbitals on all the atoms and molecules are oriented in random directions. With the huge numbers you find in a macroscopic "object", it all averages out to basically zero.

It can be easier to visualize if you think of the axes of rotation rather than the circles. They're all jumbled up in every direction.

In a ferromagnetic material all those axes are aligned, but the rotation is in randomly-distributed opposite directions so it still cancels out. But if the material gets magnetized, this happens by flipping them so they're all aligned the same direction.

And then it produces macroscopic effects, like what you're referring to.