General relativity is a 100% deterministic theory. If you can predict the coin toss in a Newtonian environment, you can predict it in a relativistic environment.*
The key thing that makes such a discussion is the idea of Lyapunov time. A coin toss happens quickly, so we can ignore anything which creates chaos on a timescale larger than that (okay, its a bit more nuanced than that... but it's a decent first pass). Relativity affects lots of things, like the paths of the planets, but the chaotic elements of those systems are on much larger time scales.
Which leaves just the relativistic effects on the coin itself. Well, we can calculate a Lorentz factor for the coin. $\gamma=\sqrt{\frac{1}{1-\frac{v^2}{c^2}}}$. Papers have approximated the velocity of a coin somewhere on the order of 3m/s to 5m/s, so we'll use the bigger one for our calculations. Plugging in $v=5m/s$, we get $\gamma=1.000000000000000138889$. That's a relativistic effect on the order of $10^{-16}$. That's really small. You can't even use normal programs to compute those effects, because that's on the order of a IEEE-754's Unit of Least Precision. Rounding errors happen on that scale.
How small of an effect is it? Well, Jupiter's gravitational pull on the coin is on the order of $10^{-7}$ times that of Earth. So when you get to that level of determinism, you need to include Jupiter in your calculations, and you're still 9 orders of magnitude. In fact, the gravitational effect of Pluto will matter, at $10^{-9}$ or so. A micro-asteroid on the scale of a 100 nanograms hanging out in the asteroid belt will have an effect on par with the relativistic effects you are considering.
So yes, it adds some complexity. No indeterminism, because general relativity is deterministic, and the scale of its effects are quite literally "astronomically small."
*. Okay, I lied a bit. In theory the extra non-linearity could lead to better mixing of the orbits. One might be able to construct a system which is stable under Newtonian physics but chaotic under relativistic physics, but in order to physically construct the experiment, you would need to be able to measure the initial conditions to the absurd levels described here or have a coin at a non-trivial fraction of the speed of light (or flip the coin near a black hole, as Anders Sandberg suggests tongue-in-cheek)