It appears to be a dynamically allocated IP address for a customer of Telefónica who is, as far as I understand, a Spanish ISP.
If what that user did was thoroughly evil to the point of being illegal, then you could complain, launch the judicial machinery, and force them to retaliate on the offender. Otherwise, there is not much to do; you cannot block him efficiently because dynamic IP may change. To some extent, that's what you deserve by accepting that anonymous visitors post messages to your site: if you allow even the worst morons to post on your site, well, they will.
Edit: actually, there is a lot you can technically do, but it would be both illegal and risky. For instance, if the perpetrator comes back and is an amateur (i.e. a real human using a real Web browser) then you could track him with cookies, inject hostile Javascript in what your server sends him, and things like that. But that's uncourteous, somewhat puerile, forbidden by Law (you are not supposed to "fight back"), and has a high risk of collateral damage. Quite possibly, the IP you saw was that of an innocent bystander who just happens to have a computer infected with malware, turning it into a relay host for evildoers.