You need to save the enumerate contents in a \vbox:
\setbox\enumbox\vbox{% …
Though, the \centering won’t work because the box is—due to enumerate’s nature— \linewidth wide.
Using it without \centering results in an overfull \hbox because the paragraph indention is inserted as usual.
Solution A
It seems, that in your case you simply could define a macro as
\newcommand*{\enummacro}{\begin{enumerate} … \end{enumerate}}
and use that inside a TikZ node. Advantage: The node would not be \linewidth wide but only as wide as you would have specified.
Solution B
You could measure the width of the list elements (assuming that they all fit on one line width-wise).
Here, I opted for an easier list defining and processing solution, namely
\newcommand*{\mylist}{Title,Abstract,Keywords,Outline}
The \mylist macro only contains the comma-separated elements.
The \getWidthOf macro needs \tikz@textfont and the smuggle macro to be usable inside a tikzpicture (no warranties here).
Solution C
As the enumerate environment introduces vertical and horizontal space which with I do not want to deal and also because the following looks better and is easier to maintain, yet another solution but with a simple tabular.
Code A (enumerate with guessed width)
\documentclass[a4paper,12pt]{article}
\usepackage{tikz}
\newcommand{\enummacro}{%
\begin{enumerate}
\item Title
\item Abstract
\item Keywords
\item Outline
\end{enumerate}}
\newsavebox\enumbox
\begin{document}
\setbox\enumbox\vbox{\enummacro}
\noindent\usebox\enumbox
\begin{tikzpicture}
\node[draw, text width=8em, align=center] {\enummacro};
\end{tikzpicture}
\end{document}
Output (enumerate with guessed width)

Solution B (properly measured enumerate)
\documentclass[a4paper,12pt]{article}
\usepackage{tikz}
\newcommand*{\mylist}{Title,Abstract,Keywords,Outline}
\newlength{\widthOfWidestElement}
\makeatletter
\def\qrr@smuggle@length@through@interruptpgfpicture#1\endpgfinterruptpicture{%
\edef\@tempa{\the#1}%
\expandafter\endpgfinterruptpicture\expandafter#1\@tempa}
\newcommand*{\getWidthOf}[1]{%
\pgfinterruptpicture
\setlength{\widthOfWidestElement}{0pt}%
\@for\@element:=#1\do{%
\sbox0{\tikz@textfont\@element}%
\ifdim\wd0>\widthOfWidestElement\widthOfWidestElement=\wd0\fi
}%
\qrr@smuggle@length@through@interruptpgfpicture\widthOfWidestElement
\endpgfinterruptpicture
\advance\widthOfWidestElement\itemindent
\advance\widthOfWidestElement\leftmargin
\advance\widthOfWidestElement\rightmargin
}
\newcommand*{\makeEnumerate}[1]{%
\enumerate % maybe better output with
% \parskip\z@
\@for\@element:=#1\do{%
\item \@element
}
\endenumerate
}
\makeatother
\begin{document}
\begin{tikzpicture}
\getWidthOf{\mylist}
\node[draw, text width=\widthOfWidestElement, align=center] {\makeEnumerate\mylist};
\end{tikzpicture}
\end{document}
Output B (properly measured enumerate)

Code C (tabular)
\documentclass[a4paper,12pt]{article}
\usepackage{tikz,array}
\newcommand*{\mylist}{Title,Abstract,Keywords,Outline}
\makeatletter
\newcommand*{\makeFakeEnumerate}[1]{%
\begingroup
\def\@temptabbody{}%
\setcounter{enumi}{0}%
\@for\@element:=#1\do{%
\expandafter\g@addto@macro\expandafter\@temptabbody\expandafter{\expandafter&\@element \\}}%
\tabular{>{\refstepcounter{enumi}\theenumi.}rl}
\@temptabbody
\endtabular
\endgroup
}
\makeatother
\begin{document}
\begin{tikzpicture}
\node[draw] {\makeFakeEnumerate\mylist};
\end{tikzpicture}
\end{document}
Output C (tabular)

enumerateentries to get the longest so that the box width may be determined automatically? Thanks. – chandra Mar 30 '13 at 14:37\newcommand*{\enummacro}{Title,Abstract,Keywords,Outline}as a list which will be used to get measured and to set up theenumerateenvironment? What is your end goal here? Maybe you could use atabularwith two columns of which the last one is a line-breaking-disallowinglcolumn. – Qrrbrbirlbel Mar 30 '13 at 15:18tabularoutput C that mimics anenumerateenvironment but which is easy to maintain. I am using themakeFakeEnumeratecommand in a manuscript and the result here is exactly what I wanted: http://i.imgur.com/FKAosW9.png. I guess that I could adapt this to display bullet-points in amakeFakeItemizecommand as well. Thank you very much. – chandra Apr 01 '13 at 10:57