I must be doing something wrong, but I follow the example precisely (as precisely as someone could reasonably guarantee) and LaTeX yet refuses to compile the document:
ERROR: LaTeX Error: Illegal character in array arg.
--- TeX said ---
See the LaTeX manual or LaTeX Companion for explanation.
Type H <return> for immediate help.
...
l.4 \begin{tabular}{>{\bfseries}rl}
--- HELP ---
There is an illegal character in the argument of an array or tabular
environment, or in the second argument of a \multicolumn command.
Here is my MWE:
\documentclass{article}
\begin{document}
\begin{tabular}{>{\bfseries}rl}
hi & bye
\end{tabular}
\end{document}