Is this the expected result?

MWE:
\documentclass[12pt]{book}
\begin{document}
\begin{titlepage}
\newcommand{\HRule}{\rule{\linewidth}{0.5mm}}
\centering
{\LARGE\scshape PONDICHERRY ENGINEERING COLLEGE\\[1.5cm]}
{\Large\scshape CASE TOOLS LABORATORY\\[0.5cm]}
{\large\scshape SOFTWARE REQUIREMENTS SPECIFICATION\\[0.5cm]}
\HRule \\[0.4cm]
{\huge\bfseries WEB BLOG\\[0.4cm]}
\HRule \\[1.5cm]
\begin{minipage}{0.4\textwidth}
\begin{flushleft} \large
\emph{Author:}\\
Subham \textsc{Soni}
\end{flushleft}
\end{minipage}
~
\begin{minipage}{0.4\textwidth}
\begin{flushright}
\emph{Supervisor:}\\
\textsc{Mr.M. Thirumaran}
\end{flushright}
\end{minipage}\\[4cm]
{\Large \today \\[3cm]}
\vfill
\end{titlepage}
\end{document}
EDIT
About the logo, I've downloaded the image http://www.pec.edu/images/pecemblem.png from the PEC site (hope they don't mind) and this is how you can insert the logo:
\documentclass[12pt]{book}
\usepackage{graphicx}
\begin{document}
\begin{titlepage}
\newcommand{\HRule}{\rule{\linewidth}{0.5mm}}
\centering
\includegraphics[scale=0.75]{pecemblem}\\[.5cm]
{\LARGE\scshape PONDICHERRY ENGINEERING COLLEGE\\[1.5cm]}
{\Large\scshape CASE TOOLS LABORATORY\\[0.5cm]}
{\large\scshape SOFTWARE REQUIREMENTS SPECIFICATION\\[0.5cm]}
\HRule \\[0.4cm]
{\huge\bfseries WEB BLOG\\[0.4cm]}
\HRule \\[1.5cm]
\begin{minipage}{0.4\textwidth}
\begin{flushleft} \large
\emph{Author:}\\
Subham \textsc{Soni}
\end{flushleft}
\end{minipage}
~
\begin{minipage}{0.4\textwidth}
\begin{flushright}
\emph{Supervisor:}\\
\textsc{Mr.M. Thirumaran}
\end{flushright}
\end{minipage}\\[4cm]
{\Large \today \\[3cm]}
\vfill
\end{titlepage}
\end{document}
Output:

Some hints
You have to use \centering and not \center. The latter is more or less equivalent to \begin{center} (see \center and \centering and the linked duplicate).
The strange behavior with the overlapped title happens because when you change font attributes inside a group you have to terminate the paragraph otherwise it doesn't end (see for example Incorrect line spacing when using \Large in a center environment). So encasing \\[...] in the group solves the problem.
Since you are already using groups with braces like {\Large ....} it is better to use constructs like {\Large\scshape ....} rather than \textsc{\Large ....}.
Nothing to say about \end{document![}][1] since it is obviously an error while you were trying to insert an image....
\end{document![}][1]is just a typo. – Speravir Jan 12 '14 at 17:45