If I understand your setup correctly, you have two separate standalone documents, say, doca.tex and docb.tex, and you'd like to cross-reference an item (e.g., a chapter) from Document A in Document B.
One way to achieve this objective is to use the xr-hyper package, which is part of the hyperref bundle. The xr-hyper pacakge works exactly like the xr package. E.g., suppose doca.tex consists of the following code:
%% doca.tex
\documentclass{report}
\usepackage{hyperref,xr-hyper}
\begin{document}
\chapter{Beginning of Doc A} \label{doca:chap:1}
In the beginning, \dots
\end{document}
Note that both the hyperref and xr-hyper packages are loaded. Compile it twice and make sure not to delete the file doca.aux as it contains important cross-referencing information.
Suppose further that docb.tex contains the following code:
\documentclass{report}
\usepackage[colorlinks=true]{hyperref}
\usepackage{xr-hyper}
\externaldocument{doca}
\begin{document}
\chapter{End of Doc B}
As we argued in \autoref{doca:chap:1} of Document A, \dots
\end{document}
The crucial extra instruction is \externaldocument{doca}: it tells LaTeX to search in doca.aux for labels to cross-references. The directive \autoref{doca:chap:1} will then successfully create a cross-reference to "chapter 1" of Document A.

xr-hyperpackage are the same as for thexrpackage. I'll post a quick answer to explain its functioning. – Mico Apr 14 '14 at 23:28