\begin{document}
\pagestyle{empty}
% Define block styles
\tikzstyle{decision} = [diamond, draw, fill=white!20,
text width=5.5em, text badly centered, node distance=5cm, inner sep=0pt]
\tikzstyle{block} = [rectangle, draw, fill=white!20,
text width=5em, text centered, rounded corners, minimum height=4em]
\tikzstyle{line} = [draw, -latex']
\tikzstyle{cloud} = [draw, ellipse,fill=red!20, node distance=5cm,
minimum height=5em]
\begin{tikzpicture}[node distance = 4cm, auto]
% Place nodes
\node [block] (sume) {1.-Sume variables de holgura (forma estándar)};
\node [block, below of=sume] (calcu) {2.-Calcule una primer solución básica factible};
\node [decision, below of=calcu] (decide) {3.-¿Existe una solución básica factible adyacente que sea mejor?};
\node [block, right of=decide, node distance=5cm] (no) {5.-Entonces la solucion basica factible actual es óptima};
\node [block, left of=decide, node distance=5cm] (yes) {4.-Entonces calcule el valor de la funcion $Z$ para la nueva solucion básica factible};
% Draw edges
\path [line] (sume) -- (calcu);
\path [line] (calcu) -- (decide);
\path [line] (decide) -- node {Si} (yes);
\path [line] (yes) -| (calcu);
\path [line] (decide) -- node {No} (no);
\end{tikzpicture}
\end{document}

This is the first time I'll create a flowchart in Latex, I did this so far, and the result looks terrible. Can someone help me to make this look similar to the image I have?.

- This is the result from what I did, the problem is that the arrow that goes from 4 to 2 is flip, How can I solve that
- What instruction makes the arrow look thicker?
Code