TeX excels at laying out a page with well-formed paragraphs, so let the program do what it does best. Leave a blank line between paragraphs in your source code. TeX interprets the blank line as a \par instruction, so you don't need to write that command explicitly. The \\ command is simply not intended for use in ordinary text; instead it is used in tabular and verse environments, among others.
If you want to use white space as an occasional section break, then you could define \newcommand{\sectionbreak}{\vspace*{\baselineskip}} in the preamble and then just write \sectionbreak in the document where you need it. (You can also use larger values like 2\baselineskip or you could use the commands \smallskip, \medskip, or \bigskip.)
...end of paragraph.
\sectionbreak
Next paragraph...
If you want white space between every paragraph as part of the design of your document, then really you want to increase the value of \parskip, but doing that manually can cause problems because TeX relies on there being a certain amount of "glue" to adjust between vertically stacked boxes in order to lay out the page. Instead, you can simply write \usepackage{parskip} and the package will adjust the values properly. In the memoir class, there is a \nonzeroparskip command that does something similar.
In a least-optimal scenario (because it doesn't separate content from presentation and locks you into a particular layout), if you have a short series of text lines which you would like separated by white space, you can use a tabular environment. You can use \\[1ex] at the end of the line to get an extra blank line. (With the booktabs package you can just write \addlinespace.)
\begin{tabular}{l}
First line\\[1ex]
Second line\\
\end{tabular}
parskippackage. – jon Apr 28 '15 at 20:15parskippackage or equivalent options provided by certain "heavyweight" document classes. (Edit: ninja'd by jon... :-)) – Paul Gessler Apr 28 '15 at 20:16parskippackage fills that need in your case. – jon Apr 28 '15 at 20:23parskip, you can put e.g.\smallskip,\medskipor\bigskipbefore the blank line (or\par) to insert extra spacing. This is much better than\par~\parbut should nonetheless be used with caution since it is less maintainable and makes it harder to achieve consistent formatting. – cfr Apr 28 '15 at 23:10