The problem is the underscore. Use x86\textunderscore 64 or x86\_64.
\documentclass[a4paper,12pt]{article}
\begin{document}
\title{Kubuntu Setup}
Don't forget your architecture is not i386, but x86\textunderscore 64. Better to use \texttt{\$(uname -i)} instead of manually specifying this
\end{document}
I also change tt to \texttt. Alternative you can use \ttfamily. For more information about this topic read l2tabu
Quoted from l2tabu:
Why not use obsolete commands? Obsolete commands do not support
LATeX2ε’s new font selection scheme, or NFSS. {\bf foo}, for
example, resets all font attributes which had been set earlier before
it prints foo in bold face. This is why you cannot simply define a
bold-italics style by {\it \bf Test} only. (This definition will
produce: Test.) On the other hand, the new commands
\textbf{\textit{Test}} will behave as expected producing:
Test. Apart from that, with the former commands there is no
‘italic correction’, cf. for instance halfhearted ({\it
half}hearted) to halfhearted (\textit{half}hearted).