I do not understand what you mean by cant place them right or note cant be placed in centre. See if the following result is suitable for you. The images have their own captions labeled a,b... and the groups have their common captions. The captions are centered.
If you want sub figures to be grouped (ie., automatically numbered a,b,c...) they have to be in the same figure environment. Putting each sub figure in its own figure environment defeats the purpose.
\documentclass[a4paper,twocolumn,twoside,10pt]{article}
\usepackage{mwe}
\usepackage{subcaption}
\usepackage{floatrow}
\begin{document}
\blindtext
\begin{figure}[h]
\begin{subfigure}[]{0.95\textwidth}
\includegraphics[width=1\textwidth]{example-image-a}
\caption{subm image A}
\end{subfigure}
\begin{subfigure}[]{0.95\textwidth}
\includegraphics[width=1\textwidth]{example-image-b}
\caption{sub image B}
\end{subfigure}
\caption{common caption}
\end{figure}
\vfill\eject
\blindtext
\begin{figure}[h]
\begin{subfigure}[]{0.95\textwidth}
\includegraphics[width=1\textwidth]{example-image-c}
\caption{sub image C}
\end{subfigure}
\begin{subfigure}[]{0.95\textwidth}
\includegraphics[width=1\textwidth]{example-image-a}
\caption{sub image 4}
\end{subfigure}
\caption{common caption}
\end{figure}
\end{document}

Update
Based on the answers in the links, I have modified the example. I don't know whether it will be useful in your actual project since it requires multicols package. If your report is several pages long, It may be easier to use the figure* method and manually shift the figure* command near text on the previous page so that finally it appears on the correct page.
\documentclass[a4paper,twoside,10pt]{article}
\usepackage{mwe}
\usepackage{subcaption}
\usepackage{multicol}
\begin{document}
\begin{multicols}{2}
\blindtext
\blindtext
\end{multicols}
\begin{figure}[hb]
\begin{subfigure}[]{0.4\textwidth}
\includegraphics[width=1\textwidth]{example-image-a}
\caption{subm image A}
\end{subfigure}
\hfill
\begin{subfigure}[]{0.4\textwidth}
\includegraphics[width=1\textwidth]{example-image-b}
\caption{sub image B}
\end{subfigure}
\caption{common caption}
\end{figure}
\begin{figure}[hb]
\begin{subfigure}[]{0.4\textwidth}
\includegraphics[width=1\textwidth]{example-image-c}
\caption{sub image C}
\end{subfigure}
\hfill
\begin{subfigure}[]{0.4\textwidth}
\includegraphics[width=1\textwidth]{example-image-a}
\caption{sub image 4}
\end{subfigure}
\caption{common caption}
\end{figure}
\end{document}

{}button to mark it as latex code. As for the images, you can replace them byexample-image-a(or others) which is a sample image automatically installed in your system. That way you don't have to upload your own images here. – AJN Mar 20 '16 at 05:19